BINAP 1.1′-Binaphthyl-2.2′-diphemyl phosphine CAS 98327-87-8

Sinónimos

BINAP
Binap
(?-Binap
1.1′-Binaphthyl-2.2′-Diphemyl Phosphine
2,2′-BIS(DIPHENYLPHOSPHINO)-1,1′-BINAPHTHYL
(?-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
Rac-2,2-Bis(Diphenylphosphino)-1,1-Binaphthyl
2,2′-Bis(diphenylphosphino)-1,1′-binaphthalene
Racemic-2,2′-bis(diphenylphosphino)-1,1′-binaphthy
racemic-2,2′-Bis(diphenylphosphino)-1,1′-binaphthyl
S(-)-(1,1′-Binaphthalene-2,2′-Diyl)Bis(Diphenylphosphine)
RACEMIC-2,2”-BIS(DIPHENYLPHOSPHINO)-1,1”-BINAPHTHYL BINAP
2,2′-Bis-(diphenylphosphino)-1,1′-binaphthyl (Racemic BINAP)

CAS

98327-87-8

EINECS

619-338-0

InChIKey

MUALRAIOVNYAIW-UHFFFAOYSA-N

Masa Molar

622.69

Punto de fusión

283-286°C(lit.)

punto Boling

724.3±55.0 °C(Predicted)

Disolución del agua

Soluble in tetrahydrofuran, benzene and dichloromethane. Slightly soluble in ether, methanol and ethanol. Insoluble in water.

Solubilidad

Chloroform (Slightly, Sonicated), Dichloromethane (Slightly, Heated),

Apariencia

White to beige powder

color

White to light beige

Merck

14,1223

BRN

5321443

Condición de almacenamiento

Conservar a la luz, en un ambiente inerte y a temperatura ambiente

Sensible

Sensible al aire

MDL

MFCD00010805

Propiedades físicas y químicas

Melting point 280-285°C.

Uso

Used for asymmetric hydrogenation catalysis, carbonyl reduction, etc. A ligand for the palladium-catalyzed arylamine coupling reaction for the preparation of desmethylthio-colchicine? cicatine. It can be used in combination with Cu(II) to catalyze the addition reaction of arylsulfonamide to produce styrene and olefins. It can also be used for palladium-catalyzed tripyridyl amine reaction.

Códigos de riesgo

36/37/38 – Irritating to eyes, respiratory system and skin.

Descripción de seguridad

S22 – Do not breathe dust.
S24/25 – Avoid contact with skin and eyes.
S37/39 – Wear suitable gloves and eye/face protection
S26 – In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.

WGK Alemania

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