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Oxalyl Chloride CAS No. 79-37-8

79-37-8 - Names and IdentifiersNameOxalyl chlorideSynonymsOxaloylchlorideOXALYL CHLORIDEOxalyl

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Contenido

79-37-8 - Names and Identifiers

NombreOxalyl chloride
SinónimosOxaloylchloride
OXALYL CHLORIDE
Oxalyl chloride
Oxalicdichloride
Oxaloyl chloride
oxalicdichloride
Oxaloyl Chloride
Oxalic Dichloride
OXALYL DICHLORIDE
Oxalyl Dichloride
Oxalic dichloride
Ethanedioyl Chloride
OXALIC ACID CHLORIDE
Oxalic Acid Chloride
Oxalic Acid Dichloride
Ethanedioyl Dichloride
OXALIC ACID DICHLORIDE
Oxalyl chloride solution 2.0 M in methylene chloride
CAS79-37-8
EINECS201-200-2
InChIInChI=1/C2Cl2O2/c3-1(5)2(4)6
InChIKeyCTSLXHKWHWQRSH-UHFFFAOYSA-N

79-37-8 - Physico-chemical Properties

Fórmula MolecularC2Cl2O2
Masa Molar126.93
Densidad1.5 g/mL at 20 °C (lit.)
Punto de fusión-10--8 °C (lit.)
punto Boling62-65 °C (lit.)
Punto Flash176-178°C
Disolución del aguareacts
Presión de vapor150 mm Hg ( 20 °C)
Vapor Density4.4 (vs air)
AparienciaLiquid
colorAPHA: 0-150
Odorpenetrating odor
Exposure LimitACGIH: TWA 50 ppmOSHA: TWA 25 ppm; STEL 125 ppmNIOSH: IDLH 2300 ppm
Merck14,6914
BRN1361988
Condición de almacenamientoStore Cold
EstabilidadStable. Incompatible with bases, alcohols, steel, oxidizing agents, alkali metals. Moisture sensitive. Reacts violently with water, liberating toxic gas.
SensibleSensible a la humedad
Índice de refracciónn20/D 1.429(lit.)
Propiedades físicas y químicascolored fuming liquid with pungent odor. Water and ethanol can be vigorously decomposed, cooled to -12 deg C that condensed into white crystalline blocks. Decomposition and evolution of carbon monoxide occurred at 60 °c. Soluble in ether, benzene and chloroform, with corrosive and lacrimal.
UsoMainly used in the synthesis of pesticides and pesticide intermediates and for the synthesis of other organic chlorides

79-37-8 - Risk and Safety

Códigos de riesgoR14 - Reacts violently with water
R20 - Harmful by inhalation
R29 - Contact with water liberates toxic gas
R34 - Causes burns
R40 - Limited evidence of a carcinogenic effect
R23/24/25 - Toxic by inhalation, in contact with skin and if swallowed.
R37 - Irritating to the respiratory system
R35 - Causes severe burns
R23 - Toxic by inhalation
Descripción de seguridadS26 En caso de contacto con los ojos, enjuagar inmediatamente con mucha agua y buscar asesoramiento médico.
S36/37/39 Usar ropa de protección adecuada, guantes y protección ocular/facial.
S43 - In case of fire use ... (there follows the type of fire-fighting equipment to be used.)
S45 - In case of accident or if you feel unwell, seek medical advice immediately (show the label whenever possible.)
S8 - Keep container dry.
S24 / 25 - evite el contacto con la piel y los ojos.
S23 - Do not breathe vapour.
S27 - Take off immediately all contaminated clothing.
UN IDsUN 2927 6.1/PG 2
WGK Alemania2
RTECSKI2950000
FLUKA BRAND F CODES9-19-21
TSCAYes
Número de aranceles29171990
Hazard NoteToxic/Corrosive/Store Cold/Lacrymatory
Clase de peligro8
Packing GroupII

79-37-8 - Reference Information

Decomposition176-178 ºC
Introductionoxalyl chloride is a kind of synthetic intermediate of medicine, pesticide, in medicine used as raw materials for the synthesis of antibiotics, in the coating used as raw materials for methacryloylphthalein isocyanate, pesticide industry for the synthesis of ultra-efficient sulfonylurea herbicides benzyl Huanglong, plant growth regulators, etc, it is widely used.
Usooxalyl chloride, also known as oxalyl chloride, is an intermediate of benzoylurea insecticides, such as fluifolide, it is also an intermediate of sulfonylurea herbicides such as metsulfuron-methyl, bensulfuron-methyl, pemisulfuron-methyl and the like. In addition, it can also be used in medicine as a raw material for the synthesis of antibiotics.
used in the synthesis of organic chlorides. Used as a military gas.
commonly used as a military use of toxic gases, but also as a chlorinating agent in organic synthesis
for the preparation of organic chlorides
mainly used for sulfonylurea herbicides, pesticides, an important raw material for the synthesis of pharmaceutical chemistry intermediates, but also polyamide, Chemical Luminescence agent, high quality acylating agents in chemical industry such as liquid crystals
are mainly used for the synthesis of pesticides and pesticide intermediates and for the synthesis of other organic chloride
analysis reagents. It is mainly used as an important raw material intermediate for the synthesis of sulfonylurea herbicides, pesticides and medicinal chemistry. It is also a high quality acylating agent in the chemical industry such as polyamide, Chemical Luminescence agent, liquid crystal and other fields.
production methodprepared by the reaction of anhydrous oxalic acid and phosphorus pentachloride.
The preparation method is to obtain oxalyl chloride by reacting oxalic acid with phosphorus pentachloride. The reaction equation is shown in the figure. After phosphorus pentachloride and anhydrous oxalic acid are mixed uniformly, they are slowly heated to about 64 ° C. And reacted until almost no hydrogen chloride is released, and the obtained crude product is further subjected to rectification to obtain oxalyl chloride.


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