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Photoinitiator 784/Bis-2,6-difluoro-3-pyrrolylphenyltitrocene CAS No.:125051-32-3

125051-32-3 - Names and IdentifiersNameBis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene

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Contenido

125051-32-3 - Names and Identifiers

NombreBis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene
SinónimosLS 784
)phenyl]-
Irgacure 784
photo sensitizer 784
cyclopenta-1,3-diene
bis(2,6-difluoro-3-pyrrol-1-yl-phenyl)titanium
bis(cyclopentadienyl)bis(2,6-difluoro-3-(1H-pyrro
BIS(2,6-DIFLUORO-3-(1-HYDROPYRROL-1-YL)PHENYL)TITANOCENE
Bis(2,6-Difluoro-3-(1-Hydropyrrol-1-Yl)Phenyl)Titanocene
Bis(2,6-difluoro-3-(1-hydropyrro-1-yl)-phenyl)titanocene
titanium,bis(.eta.5-2,4-cyclopentadien-1-yl)bis[2,6-difluoro-3-(1h-pyrrol-1-yl
Bis(.eta.5-2,4-cylcopentadien-1-yl)-bis(2,6-difluoro-3-(1H-pyrrol-1-yl)-phenyl)titanium
Bis(.eta.5-2,4-cylcopentadien-1-yl)-bis(2,6-difluoro-3-(1H-pyrrol-1-yl)-phenyl) titanium
CAS125051-32-3
EINECS412-000-1
InChIInChI=1/2C10H6F2N.2C5H6.Ti/c2*11-8-3-4-10(9(12)7-8)13-5-1-2-6-13;2*1-2-4-5-3-1;/h2*1-6H;2*1-4H,5H2;/rC20H12F4N2Ti.2C5H6/c21-13-5-7-15(25-9-1-2-10-25)17(23)19(13)27-20-14(22)6-8-16(18(20)24)26-11-3-4-12-26;2*1-2-4-5-3-1/h1-12H;2*1-4H,5H2

125051-32-3 - Physico-chemical Properties

Fórmula MolecularC30H12F4N2Ti
Masa Molar524.3
Densidad1.43 at 20℃
Punto de fusión160-170°C
Presión de vapor0-0.001Pa at 25-50℃
AparienciaPolvo
Condición de almacenamientobelow 5° C
Sensible4: no reaction with water under neutral conditions

125051-32-3 - Risk and Safety

Códigos de riesgoR36 / 37 / 38 - irrita los ojos, el sistema respiratorio y la piel.
R51/53 - Toxic to aquatic organisms, may cause long-term adverse effects in the aquatic environment. 
R62 - Possible risk of impaired fertility
R48/22 - Harmful danger of serious damage to health by prolonged exposure if swallowed.
R11 - Altamente inflamable
Descripción de seguridadS26 En caso de contacto con los ojos, enjuagar inmediatamente con mucha agua y buscar asesoramiento médico.
S36/37/39 Usar ropa de protección adecuada, guantes y protección ocular/facial.
S61 Evitar la liberación al medio ambiente. Consulte las instrucciones especiales / hojas de datos de seguridad.  
S36/37 - Wear suitable protective clothing and gloves.
S33 - tomar medidas preventivas para prevenir la descarga estática.
S22 - No inhalar polvo.
S7 - Keep container tightly closed.
TSCAYes

125051-32-3 - Reference Information

LogP9.5 at 20℃
surface tension72.4mN/m at 10g/L and 20 ℃
EPA chemical informationInformation provided by: ofmpub.epa.gov (external link)
Introducciónphotoinitiator 784 is a very active orange solid photoinitiator with good photoactivity, thermal stability and low toxicity. as a reactive diluent, it is mainly used for UV and visible light curing of unsaturated prepolymers together with single or multi-functional vinyl monomers and oligomers. Especially suitable for imaging or information storage photosensitive resin curing in high-tech content and high value-added fields, information storage equipment, such as photosensitive layer, holography, laser direct imaging, three-dimensional flat printing, etc. It can initiate the polymerization reaction of unsaturated resin under the action of visible light or ultraviolet light. Curing can be carried out under ultraviolet light, visible light or even suitable laser irradiation, such as Ar-laser (488nm) and FD-Nd/YAG-laser (532nm). The curing performance obtained by isolating oxygen during the curing process.
advantages1. it has high photosensitivity and high sensitivity from ultraviolet to visible light
2. it can effectively cure thick films and can cure coatings with a thickness of more than 70 μm
3. it is suitable for dark light curing coatings
4. safety, environmental protection and hygiene
featuresits photoinitiation process is neither a cracking type nor a hydrogen capture type. Due to the special photoinitiation mechanism of 784, it is very suitable for thick coatings and dark curing systems. It can cure coatings with a thickness of more than 70um and black, red and high pigment coatings; plus 784 ultra-wide ultraviolet and visible light absorption The spectrum band can make full use of the light source, so it has high photosensitive sensitivity and photoinitiation activity. In addition, the photolysis fragments are complexed by acrylate and do not migrate to the surface, so they are safe and environmentally friendly. In addition, 784 have good thermal stability.


table 1 shows the specifications and physical characteristics of photoinitiator 784
usoUV paint, UV ink, UV adhesive


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